Influence of Copper and Selenium Atoms on the Crystal Structure of Ga0.5In1.5S3 with Partial Replacement of Gallium and Sulfur Atoms with Copper and Selenium Atoms
It was found that the structure of Ga0.5In1.5S3 crystals, characterized by TOTE and TOTTOOE structural types, with the replacement of 1/3 of the gallium atoms by copper atoms, the Gu0.5Ga0.33In1.5S3 structure becomes the TOTTE type (a = 3:861Ȧ , c = 30:915 Ȧ, sp. gr. P63mc), and with the subsequent replacement of 1/6 of the sulfur atoms by selenium, the Gu0.5Ga0.33In1.5S2.5Se0.5 structure becomes the TOTTE type (polytype 1T: a = 3:866Ȧ, c = 18:695Ȧ, sp. gr. P3m1 and polytype 3R: a = 3:866 Ȧ, c = 56:085 Ȧ, sp. gr. R3m). The advantage of a new continuous electron diffraction rotation method for studying samples consisting of mixtures of polytypes with large weight differences is presented.