The Structural and Magnetic Properties of Magnetite Nanoparticles Doped with Rare Earth Elements Dy and Sm
We report a structural and magnetic study of Sm- and Dy-doped Fe3O4 nanoparticles synthesized by co-precipitation method. X-ray and neutron diffraction confirm that all samples retain a single-phase cubic spinel structure with rare earth ions incorporated into the lattice. Doping induces slight changes in lattice parameters and Fe–O bond lengths while preserving the normal spinel oxygen coordination. Magnetic refinements show that Sm3+ and Dy3+ stabilize the ferrimagnetic order and slightly enhance the ordered iron moments. SAXS measurements reveal nanoparticle sizes consistent with XRD data and indicate slight surface modifications and aggregation effects induced by doping. Overall, Sm and Dy dopants produce moderate structural changes but improve the magnetic behavior of Fe3O4 nanoparticles.